20-EPN2-017: Resolving critical uncertainties in the impact of geomagnetism on in situ cosmogenic nuclide production via long-term calibration

Visit by Gordon Bromley, University of Galway (Ireland), to TA2.9 Ion Probe Facility (IPF), CRPG (France).
Dates of visit: 17 – 21 October 2022

Report Summary: Cosmogenic nuclide (CN) surface-exposure dating (SED) has revolutionised geomorphology in recent years, enabling the direct determination of both the rate and age of Earth surface-processes. However, SED relies on strict quantification of CN production rates (PRs) for both the time-period and location in question; for many sites and times periods such data is rare. As a result, calculated exposure ages may vary significantly depending upon the assumptions and model schemes employed in calculations. The impact of geomagnetic field variability on nuclide production is particularly uncertain.

The goal of this project is to test explicitly the methods used to calculate exposure ages, and to assess their viability over space and time. To do this, we measured cosmogenic helium-3 within a series of Peruvian lavas of varying age at the Stable Rare Gas and Radiogenic Isotope Facility, CRPG (France). Paired with later Ar/Ar age determination, we are using these new cosmogenic helium data to produce a series of discrete CN production rates from a single geographic region, and so will assess the variability of nuclide production through time. Our preliminary results indicate the research plan is viable: cosmogenic helium data from single lava flows are internally consistent. Lavas analysed range in age from ~1.6 ka to ~175 ka, and so provide a dataset that spans a period sufficient to assess changes in PR and the potential impact of magnetic field variability on CN PRs. We anticipate sharing final project results within a peer-reviewed, open-access publication within the calendar year. 

Read the full scientific report, with kind permission from Gordon Bromley.

20-EPN2-053: Noble gas (³He) analyses of iridium poor marine sediments to understand the astronomic process responsible for the late Eocene meteor shower

Visit by Jörg Fritz, ZERIN (Germany), to TA2.9 Ion Probe Facility (IPF), CRPG (France).
Dates of visit: 06 – 15 April 2022

Report Summary: The project aims to understand the astronomical processes leading to the late Eocene shower of extraterrestrial (ET) material onto Earth. The ³He-carrier phases responsible for the ~ 2 million years enduring ³He anomaly will be characterised geochemically by producing a combined ³He and Ir dataset.

Here, 23 samples of marine micro-fossil ooze form the ODP 689B core, Maud Rise, Southern Ocean were measured at the CRPG Nancy noble gas laboratory. These samples cover the Eocene Oligocene transition (38 to 33 Ma) and these new data document the amplitude and duration of the  ³He_ET anomaly and confirms that the late Eocene ³He anomaly reported from the Massignano outcrop (Italy) is a global phenomenon. The here-investigated 689B micro-fossil ooze is exceptional because its low terrigenous mineral content and low iridium concentration of 5-15 ppt Ir. These Ir values are close to the expected ET contribution of 12 ppt Ir, as calculated using the current global/annual ET flux and the sedimentation rate and dry density of the 689B deposits.

The ³He data set acquired during the TA visit combined with literature data on Ir concentrations show that the flux of ³He rich ET particles increase by 4 times whereas the Ir concentrations in 689B remain at background values. New Ir data with low detection limits will further constrain the relation between ET ³He and total Ir during the late Eocene shower. ET ³He does not correlate with Ir indicating that the late Eocene ³He anomaly was caused by ³He-rich and Ir poor dust particles. The study illuminates the potential of marine micro-fossil ooze for planetary science.

20-EPN2-072: Dynamics of the early inner solar system inferred from combined 26 Al-26 Mg and Cr–Ti–O isotope systematics of non-carbonaceous chondrules

Visit by Christian Jansen, WWU Münster (Germany) to TA2.9 Ion Probe Facility (IPF), CRPG (France).
Dates of visit: 03-12 August 2022

Report Summary: The advent of non-traditional isotopic systems (e.g., Ti, Cr, Mo) revealed that chondrites—the most primitive witnesses of the early solar system—display a fundamental isotopic dichotomy, with carbonaceous chondrites (CCs) showing large nucleosynthetic anomalies relative to terrestrial standards that are not observed in non-carbonaceous chondrites (NCs). NC and CC reservoirs may thus represent the primordial inner and outer parts of the solar system, respectively. 

The scientific goal of this project is to combine several isotopic systems (O, Ti, Cr) for deciphering the conditions and chronology of chondrule formation in the NC reservoir. A key parameter of this approach is to also have access to the formation ages of these chondrules. This requires in situ measurements with a secondary ion mass spectrometer for determining the ²⁶Al ages of chondrule crystallisation.

To do so, 16 chondrules were separated from the minimally altered ordinary chondrite NWA 5206. They were split into two pieces for determining their (i) Cr and Ti isotopic compositions (bulk measurements) and (ii) O isotopic compositions and ²⁶Al ages. These chondrules show no ⁵⁴Cr or ⁵⁰Ti excesses and classical oxygen isotopic composition (with ∆¹⁷ O ranging from -1 to + 1 ‰). ²⁶Al ages are coherent with previous estimates showing that NC chondrules formed over several million years during the evolution of the inner disk.

20-EPN2-102: A new source of water from Mars

Visit by Tim Tomkinson, University of Bristol (UK) to TA2.9 Ion Probe Facility (IPF), CRPG (France).
Dates of visit: 05-09 December 2022

Report Summary: Here we have searched for a source of D-enriched Martian groundwater previously discovered in the Martian meteorite Lafayette (up to δD 4725‰) within olivine defects below the secondary mineral phyllosilicate. These groundwaters which are known flowed through this sample 670 Ma were sourced from the Martian atmosphere, or had equilibrated with it, and diffused up to ~1.5 µm into the olivine via shock-formed defects in vein walls. In this project we want to determine a calibration line to resolve the water content on the Martian olivines and find a potential location of new water within the defects.

Two 1 inch indium mounts were prepared with olivine plus glass standards and paired Martian nakhlite samples (Yamato 593, 802, 749, Lafayette and Nakhla) to confirm this source of Martian ground water. Work was conducted with Dr Johan Villeneuve and Dr Laurette Piani on the Cameca IMS 1270 E7 ion probe at CRPG, Nancy. The new obtained/formed standards provided calibration to measurements of water contents (H₂O%) within the Martian olivines and when combined with standards from CRPG δD values were roughly constrained. Owing to the unique surfaces of each Martian altered olivine it was impossible to confirm pre analyses if defects hosting water would be present in the outer olivine surfaces. Results show a location where an enriched δD was present, further investigations such as Transmission Electron Microscopy (TEM) are required to confirm this.

20-EPN2-067: Hydrogen isotope compositions of matrices in unequilibrated ordinary chondrites

Visit by Helen Grant, University of Manchester (UK) to TA2.9 Ion Probe Facility (IPF), CRPG (France).
Dates of visit: 10-21 October 2022

Report Summary: One way to study the origin of water and other volatiles which accreted onto rocky planets such as Earth during the formation of the Solar System is to study meteorites that fall from asteroids and other planetary bodies. Hydrogen isotope ratios within meteorites can be used as a tracer for the source of a body’s water, and to an extent spatial and temporal information about the formation of parent bodies. 

Previously, we measured the D/H ratios of bulk powders of a wide range of unequilibrated ordinary chondrites (UOCs), and found wide variations which did not fit into current H-distribution models. Using SIMS, we measured the H, D, C, and Si contents of the fine-grained matrix of 13 of these previously studied UOCs (only falls) ranging from types 3.00 – 3.9. Preliminary results confirm the wide previously observed spread of D/H ratios between samples, including high elevations in a handful of UOCs. C/H ratios will be used to determine the D contribution within samples specific to water, however initial observations confirm contributions from both hydrated and organic components. The results from this visit will be combined with other in-situ studies carried out at the home institution to determine exactly what phases are hosting this highly D-rich material, and how these chondrites affect models of water transport in the early Solar System.

Read the full scientific report, with kind permision from Helen Grant.

20-EPN-031: Investigating volatiles in the early Solar System through analysis of halogens in chondrules

Visit by Edward Baker, University of Manchester (UK) to TA2.9 Ion Probe Facility (IPF), CRPG (France).
Dates of visit: 13-17 December 2021

Report Summary: We have measured the concentration of halogens in the glasses of chondrules from enstatite chondrites. There is a clear correlation between Chlorine and Bromine abundances, but no clear relationship between Cl or Br and F. Iodine was not measured. In the main S is well correlated with Cl: this trend may have been modified by unintended analysis of micron scale blebs on sulphide.  Halogen profiles have been taken across a number of suitable target chondrules, for diffusion modelling, which will be presented and published in due course. The array of data for F/Cl is sub-chondritic while the Br/Cl array is super-chondritic.

Evaporation and condensation may play important roles in controlling halogen behaviour, along with partitioning between other significant reservoirs in chondrites because fluorine is likely to be compatible in a number of silicate minerals. More will be known after diffusion modelling and after the experimental partition coefficients have been determined. 

Read the full scientific report, with kind permision from Edward Baker and Rhian Jones.

21-EPN-FT1-005: Reading the sedimentary archive of discontinuity surfaces

Visit by Simon Andrieu, Aarhus University (Denmark) to TA2.9 Ion Probe Facility (IPF), CRPG (France).
Dates of visit: 18-22 October 2021

Report Summary: Discontinuity surfaces, associated with seafloor cementation, are hence of primordial importance for fully apprehending the geological record, yet they have received far less attention than the sedimentary rocks surrounding them. Fundamental problems that are still not sufficiently understood concern the lateral change of discontinuities. In this project, we tackle this issue by studying the lateral variation of five distinct discontinuity horizons present in the Middle Jurassic of the High Atlas (Morocco), where outstanding exposures permit to track these surfaces over tens of kilometres. Hence, the purpose of this work is to characterise at a high-resolution the large-scale variation of petrographic and geochemical (C, O and Sr-isotopes) properties of discontinuities (matrix and cement phases) along dip and strike of a Jurassic moderately deepening ramp. δ¹⁸O (176 values) and δ¹³C (105 values) signatures were obtained on twenty-one cements and grain types, including 14 different early calcite cements and fabrics corresponding to dogtooth cements (7), turbid synaxial cements (1) and micritic/microsparitic fabrics (6).

Data confirm that dogtooth cements can precipitate in marine phreatic, meteoric phreatic and shallow burial environments. The highly negative δ¹⁸O values of micritic fabrics and turbid synaxial cements, which form in seawater, indicate that they transformed during subsequent diagenesis (i.e during meteoric water circulation or shallow burial). It indicates that they precipitate initially with an unstable mineralogy (aragonite or high-magnesium calcite). δ¹⁸O and δ¹³C data on early cements suggest that a same discontinuity can change laterally from a subaerial exposure surface to a marine surface.

Read the full scientific report, with kind permision from Simon Andrieu.

20-EPN2-100: Spectroscopic Identification of Experimental Basalt Alteration Products Under Venus Conditions

Visit by Molly McCanta, University of Tennessee (USA), to TA2 Facility 5 – DLR Planetary Spectroscopy Laboratory (Germany).
Dates of visit: 14 – 20 October 2022

Report Summary: Experiments and thermodynamic modelling clearly show that sulfates are a common alteration product under the high temperature, CO₂-SO₂-rich conditions at the surface of Venus. The exact sulfates present depend on the original basalt composition, with anhydrite (CaSO₄) and thernardite (Na₂SO₄) having been observed in the lab (Reid et al., 2023).

Alteration rates calculated from these experiments suggest that sulfate coatings may develop geologically fast and therefore alteration coatings may obscure the original protolith. Additionally, the spectral features of these high temperature sulfates are not well constrained. Although many critical sulfate minerals are stable to temperatures > 500C, previous analytical data has generally explored sulfate-temperature spectral relations to ~100C. The surface of Venus is significantly hotter at 470C. Thus is makes sense to investigate both the effects of variable thickness sulfate coatings and the spectral properties of sulfates under Venus surface conditions to gain a better understanding of their behaviour.

The next set of Venus missions will have observational capabilities in the thermal emission spectrum (range) and high T sulfate spectra are presented in another paper (Dyar ref); here we present data for the effects of high T on visible near-infrared (VNIR) sulfate spectra. In addition, we have conducted experiments to determine the effects of sulfate coating thickness on the underlying surface spectra. The data presented may help determine future mission capabilities to both recognise and analyse sulfate-bearing materials under high T conditions as well as constrain the original, unaltered surface composition.

20-EPN-027: Characterisation of the response of an Optical Particle Counter in a simulated Martian environment

Visit by Giuseppe Mongelluzzo and Gabriele Franzese, INAF (Italy), to TA2.4 Planetary Environment Facilities (PEF), AU (Denmark)
Dates of visit: 05-09 September 2022

Report summary: The characterisation of dust is paramount in the understanding of Martian climatology. Dust significantly influences Mars global climate, interacting with the incoming solar radiation, altering the atmospheric temperature budget. Local and global dust storms can cover the planet for weeks, influencing the correct functioning of scientific instruments on the surface (The Rover “Opportunity” is the most famous example). The dynamics of dust lifting is strictly related to the wind velocity field, so its characterisation would provide important information on the characteristics of Martian winds.

The proposing team has developed an Optical Particle Counter (OPC) aimed at providing direct measurements of grain concentration and size distribution on Mars, which would be the first ever accomplished outside of Earth. The instrument is able to detect dust grains in the 0.4-20 μm diameter range. Both the breadboard and the flight model versions of the instrument have been tested in Martian environment, showing good performances.

The trip to the Planetary Environment Facilities at the University of Aarhus has allowed the verification that the instrument is correctly able to sample dust grains in its upper sensible range (up to 20 µm in grain diameter) also in presence of winds up to 20 m/s. A sandbed with embedded dust has also been created inside the Martian wind tunnel, allowing the simulation of natural saltation conditions. The instrument has been able to retrieve dust grains in all simulated conditions, both for monodispersed calibrated dust samples and for polydisperse samples.  

Read the full scientific report, with kind permission from Giuseppe Mongelluzzo.

20-EPN2-050: Turbulent suspensions of volcanic ash: an experimental simulation for eruptive and resuspension ash plumes

Visit by Jacopo Taddeucci and Elisabetta Del Bello, Istituto Nazionale di Geofisica e Vulcanologia, Rome (Italy), to TA2.4 Planetary Environment Facilities (PEF), AU (Denmark)
Dates of visit: 07-11 November 2022

Report summary: Ash Injection and settling experiments have been carried out using the environmentally controlled recirculating wind tunnel facility at Aarhus University, in order to understand the processes controlling deposition and segregation of ash from volcanic plumes at stratospheric altitudes.

Ash particles erupted from the Campi Flegrei volcano (Italy) and smaller than 63 micron were injected in the wind tunnel either from the upwind extremity in the presence of wind (1 m/s) or from the side in the absence of wind. The atmospheric pressure in the wind tunnel was systematically varied to simulate the corresponding elevation in the atmosphere from 10 to 50 km. The vertical and horizontal velocity of the particles was measured, as well as the plume opacity, proxy for particle concentration over time.

Settled particles were sampled at different times during the experiments and then analysed for their abundance and size distribution. Both the opacity measurements and the number of particles sampled over time display the decay of particle concentration over time in the suspended plume. The rate of decay is strongly dependent on the atmospheric elevation in a nonlinear way, with modest changes from 10 to 20 km elevation and much larger changes for higher elevations.

From these data we will retrieve experimentally the settling velocity of volcanic ash particles at a range of elevations that is of interest for both aviation and climate modelling implications.

Read the full scientific report, with kind permission from Jacopo Taddeucci.

20-EPN-054: Understanding large aeolian ripples on Mars through wind tunnel experiments

Visit by Simone Silvestro, INAF Osservatorio Astronomico di Capodimonte (Italy), and Hezi Yizhaq, Midreshet Ben-Gurion (Israel), to TA2.4 Planetary Environment Facilities (PEF), AU (Denmark)
Dates of visit: 04-08 April 2022

Report summary: In our experiments in the Planetary Environment Facility in Aarhus we obtained, for the first time, two superimposed ripple patterns on monodisperse sand beads in CO₂ air.

The presence of two distinct sets of aeolian sand ripples in unimodal sand suggests two formational mechanisms. Morphological characteristics such as straight crests and regular spacing point toward an impact mechanism to be responsible for the formation of the smaller (cm-scale) ripples. Conversely, the higher sinuosity of the larger (decimeter) ripples suggest a different type instability (hydrodynamic) at work. We also detect an increase in sizes for the ripples with decreasing pressure which is currently under investigation.

Collectively, our work seem to confirm the hydrodynamic nature hypothesised for the large Martian ripples.

Read the full scientific report, with kind permission from Simone Silvestro.

20-EPN2-051: Evaluation of physical parameters influencing the ice particle transportby wind in a Martian-like environment

Visit by Clémence Herny, University of Bern (Switzerland) to TA2.4 Planetary Environment Facilities (PEF), AU (Denmark)
Dates of visit: 16-20 May 2022

Report summary: The transport of ice by wind plays a major role in the surface mass balance of polar caps. Ice can be redistributed by wind due to (1) transport of ice particles and/or (2) transport of water vapour associated with sublimation/condensation. On Mars, although the low atmospheric density is less favourable for the transport of particles than on Earth, both dust and sand have been observed to be transported by wind. Despite ice aeolian landforms have been observed at the surface of the North Polar Cap of Mars, ice particle transport has not been directly observed on the Martian surface. Similarly, no laboratory studies of snow/ice particle transport under Martian-like conditions have been attempted thus far due to the complexity of the material.

In this study we propose to perform experiments in the environmental wind tunnel AWTSII at Aahrus University to study the ice particle transport in a wind-flow under Martian-like pressure and temperature conditions. The threshold shear velocity, which is a critical physical parameter for particle transportation, is determined by analysing the images of the samples acquired during the experimental runs as the wind speed was increased. The influence of ice grain sizes, pressure and temperature are investigated. Results will give constraints on the plausibility of wind driven ice particle transport on Mars.

20-EPN2-023: FLUME-ET: Fluidisation of mass flows by metastable volatiles on extra-terrestrial bodies

Visit by Lonneke Roelofs and Tjalling de Haas, Utrecht University (Netherlands) to TA2.4 Planetary Environment Facilities (PEF), AU (Denmark)
Dates of visit: 03-28 October 2022

Report summary: Martian gullies are alcove-channel-fan systems which have been hypothesised to be formed by the action of liquid water and brines, the effects of sublimating CO₂ ice or a combination of these processes. Recent activity and new flow deposits in these systems have shifted the leading hypothesis from water-based flows to CO₂-driven flows. This shift in thinking is supported by the low availability of atmospheric water under present Martian conditions and the observation that gully activity occurs at times when CO₂ ice is present.

We recently performed novel experiments in the Mars chamber at the Open University in the UK that have shown that this hypothesis holds; sediment can be mobilised and fluidised by sublimating CO₂ ice under Martian atmospheric pressure. However, if these experiments work on a larger scale and if these granular-gas flows are able to erode the underlying surface and can explain the formation of Martian gully systems over the long term remained unknown. Therefore, we conducted an additional series of experiments in a larger flume that test the capacity of CO₂-driven granular flows under Martian atmospheric conditions to erode sediment.

These experiments were conducted in a 4 m long flume in the Aarhus Mars Simulation Wind Tunnel. Our experiments show that CO₂-driven granular flows can erode loose sediment under a range of different slopes and CO₂-ice fractions. The results also show that incorporation of warmer sediment increases fluidisation of the mixture, reflected by an increase in gas pore pressure in the flow. These results thus prove that morphological evolution in the gully systems on Mars can be explained by CO₂-driven granular flows.

20-EPN-078: Effect of disperse grain size distributions on the aeolian remobilisation of volcanic ash

Visit by Allen Fries, University of Geneva (Switzerland) to TA2.4 Planetary Environment Facilities (PEF), AU (Denmark)
Dates of visit: 13-17 June 2022

Report summary: Thanks to the collaboration between the University of Geneva and the University of Aarhus through the Europlanet Research program we performed a set of experiments on the remobilisation of volcanic particles. Since removal processes of volcanic particles are relatively poorly characterised, these experiments represent a unique opportunity to study the dynamics of aeolian processes. The obtained results provide valuable information on the threshold friction velocities (i.e. wind friction velocity above which particles start to detach from deposits) of different ash compositions, fundamental for modelling and forecasting remobilisation events.

A total of 32 experiments were performed by using a setup composed of a sample plate (i.e., bed of volcanic ash exposed to gradually increasing wind friction velocities) from which particles were removed by wind and imaged using various techniques simultaneously (i.e. microscopes, and webcam)). These direct observations were combined with multiple particle collection methods to study the characteristics of remobilised particles (i.e. sediment traps and adhesive papers). A complete set of half-phi grainsize classes (from 0 to 500 μm) from 4 volcanoes were analysed. 

Preliminary results show a relation between the threshold friction velocity and the grainsize, in agreement with erosion theories. In addition, these experiments illustrate variations in threshold friction velocities as a function of magma composition: lighter particles (i.e. rhyolite) are easier to remobilise than denser particles (i.e. basalt). These results are pioneering, systematically quantifying threshold friction velocities of volcanic ash for wide grainsize and composition ranges for the first time. 

Read the full scientific report, with kind permission from Allen Fries.